Yes, they do tend to lay mostly before midmorning. I let mine out of the coop around 8 or 9. Most of them lay before this time, and by being locked in during prime laying time, the ones that haven't usually have the habit of going back into the coop to lay.
I used to feed my ducks as I locked them in for the night, after about a fortnight they used to quack loadly if I was late. I used to let them out about 7am and most eggs had been laid by then.
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